While the rest of his co-stars - including Paul Bettany and Robert Downey Jr - faced the camera for a cast photo, Captain America couldn't resist taking a look down Elizabeth's very low cut dress and didn't even try to be sneaky about it.
The 27-year-old beauty - who is rumoured to be dating another of her Marvel co-stars Tom Hiddleston - didn't look too phased by Chris' leering as she posed along with the rest of the cast managing to maintain a cool exterior despite the cringeworthy moment.
After joining the Marvel universe in Avengers: Age of Ultron, Olsen reprises her role of the Scarlet Witch (Wanda Maximoff) in the third Captain America movie and while she might look poised on the red carpet she kicks just as much butt as any other Avenger on the big screen.